Models for haemoglobin–myoglobin: studies with loosely and tightly strapped imidazole ligands
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1291-1293
- https://doi.org/10.1039/c39830001291
Abstract
Three doubly bridged FeII-porphyrins are synthesized having a cavity formed on one face by an anthracene-containing bridge and an imidazole ligand strapped across the other face; all three models bind oxygen reversibly at ambient temperature, the oxygenated form of the best system being stable for almost 2 days.Keywords
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