An alternative general preparation of 2-alkyl-1-benzostannepines and their conversion into 1-benzostibepines and 1-benzoborepines via a tin–metal exchange †
- 23 May 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 12,p. 1965-1969
- https://doi.org/10.1039/b000900h
Abstract
The 2-alkyl-1-benzostannepines 4a–g were prepared by the intramolecular hydrostannation of the tin intermediates 3 to an acetylenic moiety in one pot from (Z)-1-(o-bromophenyl)but-1-en-3-ynes 1. The obtained stannepines 4 were easily converted into the 1-benzostibepines 9, 10, 11, 12 and the 1-benzoborepines 14, 15 by tin–antimony and tin–boron exchange reactions in moderate to good yields, respectively. The 1-benzoborepines 14 and 15 are hitherto unknown heterocyclic ring systems.Keywords
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