Chemically Induced Dynamic Nuclear Polarization
Open Access
- 1 December 1970
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung A
- Vol. 25 (12) , 1957-1963
- https://doi.org/10.1515/zna-1970-1227
Abstract
NMR emission and enhanced absorption of products of radical reactions (CIDNP) is explained by nuclear spin dependent adiabatic transitions between singlet and triplet states of transient radical pairs. In magnetic fields larger than about 1 kG only S - To-transitions contribute to nuclear polarization. From a kinetic formulation of the pair mechanism equations for quantitative calculations of CIDNP patterns are derived.Keywords
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