Evidence for a (π-allyl)palladium intermediate in the quinone-based palladium-catalysed allylic acetoxylation
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 265-266
- https://doi.org/10.1039/c39940000265
Abstract
The mechanism of the quinone-based palladium-catalysed allylic acetoxylation of cyclohexene is studied using 1,2-dideuteriocyclohexene (55–70% D) as substrate; the distribution of the deuterium label in the product, determined by 1H NMR spectroscopy, is that expected for a (π-allyl)palladium intermediate.Keywords
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