Beiträge zur Chemie des Bors, 133 [1] Molekül-und Kristallstruktur von Tris(methylanilido)boran / Contributions to the Chemistry of Boron, 133 [1] Molecular and Crystal Structure of Tris(methylanilido) Borane
Open Access
- 1 June 1983
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 38 (6) , 692-695
- https://doi.org/10.1515/znb-1983-0606
Abstract
The title compound crystallizes in the rhombohedral space group R3, Z = 1. The boron atom occupies a special position on the threefold axis therefore imposing C3 symmetry to the molecule. The C2BN plane is twisted relative to the BN3 plane by 37.1°, and the BN bond length of 144.8(3) pm is on the upper limit of BN bond lengths found for other triaminoborane systems.Keywords
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