The reactions of sulphur–nitrogen species in liquid ammonia
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1479-1480
- https://doi.org/10.1039/c39880001479
Abstract
14 N N.m.r. spectroscopy reveals that liquid ammonia solutions of [S4N3]Cl or [S3N2Cl]Cl contain S3N3 – whilst solutions of S4N4 contain S3N3 – and S4N5 – and traces of other species such as S2N2 2–; the usefulness of these liquid ammonia solutions in synthesis has been established in several cases with two new complexes being characterised by X-ray crystallography.Keywords
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