The absorption spectra of benzene derivatives in the vacuum ultra-violet. I
- 26 September 1947
- journal article
- Published by The Royal Society in Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
- Vol. 191 (1024) , 22-31
- https://doi.org/10.1098/rspa.1947.0100
Abstract
New photographs of the far ultra-violet spectrum of benzene are presented. The absorption from 2000 to 1800 A ($\lambda _{\max.}$, c. 1980 A) is regarded not as a part of the much stronger absorption of peak at 1790A but as due to a separate transition. Sharp bands lying at 1790A represent the first member of a previously reported Rydberg series. The spectra of toluene, xylene, monochloro- and o-dichlorobenzene, bromobenzene, iodobenzene and pyridine are briefly described, and the shifts relative to benzene are discussed. Two Rydberg series were observed for toluene, converging to a first ionization potential of 8$\cdot $77 $\pm $ 0$\cdot $05 V.
Keywords
This publication has 2 references indexed in Scilit:
- The polarisabilities of bonds—ITransactions of the Faraday Society, 1940
- The Measurement of the Resonance, Radiation, and Ionization Potentials of Several Gases and VaporsPhysical Review B, 1922