Trapping of thiaziridinimines with N‐sulfinylamines
- 1 January 1978
- journal article
- research article
- Published by Wiley in Bulletin des Sociétés Chimiques Belges
- Vol. 87 (4) , 285-292
- https://doi.org/10.1002/bscb.19780870406
Abstract
The reactions of 4‐alkyl‐5‐arylsulfonylimino‐1,2,3,4‐thiatriazolines with N‐sulfinylamines at 60‐70° yield 3‐oxo‐5‐arylsulfonylimino‐1,34,2,4‐dithiadiazolidines 4 which are smoothly converted by hydrolysis into S‐aminoisothio‐ureas 5. In contrast, the acetyl derivative 4g hydrolyzes into thiadiazoline 7. Structure assignment of the products was based on spectral and combustion analyses, chemical reactions, and, in the case of 4e, on an X‐ray structure determination.Keywords
This publication has 13 references indexed in Scilit:
- Trapping of thiaziridinimines with imines and nitrilesThe Journal of Organic Chemistry, 1976
- Trapping of thiaziridinimines with thiocarbonyl compoundsJournal of Heterocyclic Chemistry, 1976
- The Reaction of Thiobenzoyl Isocyanates with N,N'-Diphenylsulfur DiimideHETEROCYCLES, 1976
- 5‐Oxo‐1,3λ4,2,4‐dithiadiazol ‐ ein fünfgliedriges heterocyclisches KetonAngewandte Chemie, 1975
- Trapping of thiaziridinimines with heterocumulenesThe Journal of Organic Chemistry, 1975
- 4-Alkyl-5-sulfonylimino-1,2,3,4-thiatriazolines. Interesting starting materials for the synthesis of sulfonylcarbodiimides and novel heterocyclesJournal of the American Chemical Society, 1974
- S‐Amino‐isothioharnstoffe durch nucleophile Substitution an S‐Chlor‐isothiocarbamoyl‐chloridenAngewandte Chemie, 1967
- Preparation of S‐Aminoisothioureas by Nucleophilic Substitution of S‐Chloroisothiocarbamoyl ChloridesAngewandte Chemie International Edition in English, 1967
- Die Thionylamine der aliphatischen ReiheEuropean Journal of Organic Chemistry, 1893
- Ueber die ThionylamineEuropean Journal of Inorganic Chemistry, 1891