The reactions of cerium (IV) ammonium nitrate and cobalt (III) acetate with 1,2-diphenylethanes in acetic acid. Evidence against the involvement of radical cations in the side-chain oxidation of alkylbenzenes by Co(OAc)3
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 445-446
- https://doi.org/10.1039/c39840000445
Abstract
The oxidation of 1,2- diphenylethane and 2,3-dimethyl-2,3-diphenylbutane by cerium(IV) ammonium nitrate and Co(OAc)3 in acetic acid show that a radical cation mechanism is plausible only in the reaction of the former oxidant.Keywords
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