Formation of the bidentate [Ph2SNC(Me)N(H)] ligand by metal-assisted sulfimide addition to acetonitrile; X-ray crystal structure of [Pt(Ph2SNH)(Ph2SNC(Me)NH)Cl]Cl·MeCN
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 12,p. 1081-1082
- https://doi.org/10.1039/a901783f
Abstract
In contrast to similar reactions of Cu, Co and Pd species, the platinum(II) complex [Pt(MeCN)2Cl2] reacts with Ph2SNH (ratio 1:2) in MeCN via a metal assisted addition of the sulfimide to the acetonitrile to give [Pt(Ph2SNH)(Ph2SNC(Me)NH)Cl]Cl·MeCN, the first example of a complex of the bidentate [Ph2SNC(Me)N(H)] ligand.Keywords
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