Ring contraction of cyclohexasilanes to silylcyclopentasilanes and the preparation of monofunctional nonamethylcyclopentasilanes
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 10,p. 567b-568
- https://doi.org/10.1039/c2969000567b
Abstract
Dodecamethylcyclohexasilane undergoes ring contraction with aluminium chloride as catalyst in the presence or absence of trimethylchlorosilane to give, respectively, chlorodimethylsilyl- or trimethylsilyl-cyclo-pentasilane, the former being convertible into monofunctional nonamethylcyclopentasilanes.Keywords
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