Pentamethyl- and hexamethyl-platinate(IV)

Abstract
Reactions of tetramethylbis(methyldiphenyl-phosphine)platinum(IV) or trimethylplatinum iodide with methyl-lithium in diethyl ether yield lithium hexamethyl platinate(IV); in the former case, pentamethyl(methyldi-phenylphosphine)platinate(IV) is observed as an intermediate.

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