Inter- and intra-molecular condensations of CN–and NH2–with co-ordinated acetonitrile: an amino acid synthesis. X-Ray crystal structure of [(NH3)3Co{(Me)C(NH2)(NH2CNH2)2}]Br3·2/3H2O
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 289-290
- https://doi.org/10.1039/c39780000289
Abstract
[(NH3)5CoNCMe]3+ is attacked by CN– at the nitrile C atom and addition of another CN– with two intramolecular condensations involving bound amide ions yields a tridentate bis(amidine)aminomethyl malonate chelate complex [(NH3)3Co{(Me)C(NH2)(NHCNH2)2}]-Br3·2/3H2O whose structure is reported.Keywords
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