Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6): a low valent gallium(i) carbene analogue
Top Cited Papers
- 27 September 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 20,p. 1991-1992
- https://doi.org/10.1039/b005686n
Abstract
The reaction between solvent free Li{(NDippCMe)2CH} (Dipp = C6H3Pri 2-2,6), ‘GaI’ and potassium in toluene afforded Ga{(NDippCMe)2CH} 1 which features a V-shaped, two-coordinate, six-electron gallium(I) center electronically analogous to a singlet carbene carbon.Keywords
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