First α,β-unsaturated mononuclear bisylidene complex of tungsten: synthesis and structure
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 21,p. 2455-2456
- https://doi.org/10.1039/cc9960002455
Abstract
cis-Tetracarbonyl[(1-cyclopentenyl)(N-morpholino)methylidene](2-hydroxyphenyl isocyano)tungsten(0) 5 undergoes intramolecular cyclization by deprotonation and subsequent N-alkylation to give the novel bisylidene complex 6, which is characterized by a single-crystal X-ray structure analysis.Keywords
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