Absence of rearrangement in reactions of the compounds (Me3Si)3CSiMe(OMe)I, (Me3Si)3CSiMe(OH)I, and (Me3Si)3CSi(OMe)2I with electrophilic reagents
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 10,p. 1695-1697
- https://doi.org/10.1039/p29850001695
Abstract
The compounds TsiSiMe(OMe)I and TsiSi(OMe)2I [Tsi =(Me3Si)3C] have been prepared and found, unexpectedly, to give only unrearranged products of the type TsiSiMe(OMe)Z and TsiSi(OMe)2Z (Z = Cl or Y) on treatment with ICl or with silver salts AgY. The hydroxy-iodide TsiSiMe(OH)I likewise gives only TsiSiMe(OH)CI on treatment with ICl.Keywords
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