Diphosphites as a promising new class of ligands in Pd-catalysed asymmetric allylic alkylation
- 31 May 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 12,p. 1132-1133
- https://doi.org/10.1039/b101567m
Abstract
A series of diphosphite ligands, derived from readily available D-(+)-glucose, have been used for the first time in the palladium-catalysed allylic alkylation reaction with high enantioselectivity (ee up to 95%) and activity in standard conditions.Keywords
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