Compensation and the mechanisms of electrical conduction in plasticized PVC
- 1 February 1976
- journal article
- Published by IOP Publishing in Journal of Physics D: Applied Physics
- Vol. 9 (2) , 265-272
- https://doi.org/10.1088/0022-3727/9/2/017
Abstract
An explanation of compensation effects observed in PVC plasticized by DOP is suggested. It is shown that the conductivity of the polymers can be explained in terms of two conductivity mechanisms acting in series. The first of these involves electronic conduction in the surface layers of regions of syndiotactic stereoregularity where the electrons originate from neutral vacancies, while the second involves charge transfer between these regions.Keywords
This publication has 9 references indexed in Scilit:
- Arrhenius plots for oxide samples under conditions of constant pressure and the theory of defect equilibriumJournal of Physics D: Applied Physics, 1975
- Compensation effects associated with the electrical conductivity of polyacrylonitrile polymersJournal of Physics D: Applied Physics, 1975
- Electrical conductivity of small ions in polyacrylonitrile in the glass–transition regionJournal of Polymer Science: Polymer Physics Edition, 1975
- Mechanism of dc electrical conductivity in poly(vinyl chloride)Journal of Polymer Science: Polymer Physics Edition, 1974
- Ionic Jump Distance and Glass Transition of Polyvinyl ChlorideJournal of Applied Physics, 1971
- Electrical Conductivity in Poly(vinyl Chloride)Journal of Macromolecular Science: Part A - Chemistry, 1970
- Rotational Energy Barriers and Electron Tunneling in Organic SolidsJapanese Journal of Applied Physics, 1969
- Untersuchungen zur Photoleitung in PolyvinylchloridColloid and Polymer Science, 1968
- Über die Elektrizitätsleitung anorganischer Stoffe mit ElektronenleitfähigkeitThe European Physical Journal A, 1933