Functional micellar catalysis. Part 7. Cleavage of activated enantiomeric substrates by chiral functional surfactant systems
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 8,p. 1313-1316
- https://doi.org/10.1039/p29840001313
Abstract
The cleavage of enantiomeric p-nitrophenyl derivatives of the N-methyl-N-1-[hydroxy(phenyl)methyl]-ethylcarbamate (3), the 1-methylheptyl carbonate (4) and the α-methoxyphenylacetate (5) in the presence of homomicelles of N-hexadecyl-N-methylephedrinium bromide (1) and co-micelles composed of Nα-myristoyl-L-histidine (2) and hexadecyltrimethylammonium bromide or (1) was investigated. Rate effects ranging from inhibition to large enhancements and enantioselectivities ranging from 1.0 to 3.3 were observed.Keywords
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