Thermal-expansion study of the displacive phase transitions in K2ReCl6 and K2OsCl6

Abstract
Measurements of the thermal-expansion coefficient α111 in the pseudocubic direction in single crystals of K2ReCl6 and over a wide range of temperature are reported. Pronounced anomalies are noted in the vicinity of the purely displacive phase transitions. It is concluded that it is essential to include the effects of strain interactions in a comprehensive description of these phase transitions.