A Convenient Method for Stereoselective Synthesis of β-Aminoesters. Iron(II) Iodide or Trityl Hexachloroantimonate as an Effective Catalyst in the Reaction of Ketene Silyl Acetals with Imines
- 1 June 1990
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 19 (6) , 889-892
- https://doi.org/10.1246/cl.1990.889
Abstract
In the presence of a catalytic amount of iron(II) iodide or trityl hexachloroantimonate, ketene silyl acetals smoothly react with imines to afford the corresponding β-aminoesters in good yields with anti-selectivities.Keywords
This publication has 1 reference indexed in Scilit:
- Novel stereospecific silyl group transfer reactions: practical routes to the prostaglandinsJournal of the American Chemical Society, 1989