Protiodeacetylation of porphyrins and pyrroles: a new partial synthesis of dehydrocoproporphyrin (S411-porphyrin)
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 283-284
- https://doi.org/10.1039/c39810000283
Abstract
Treatment of copper(II) complexes of acetyl-porphyrins with ethanedithiol and boron trifluoride–ether in acetic acid efficiently accomplishes deacetylation of the porphyrin system, and this reaction is demonstrated in a new partial synthesis of dehydrocoproporphyrin (S411-porphyrin); acetylpyrroles are also quantitatively deacetylated under these conditions.Keywords
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