Conformational preferences in some aryl substituted heterocyclic compounds exhibiting restricted internal rotation about C–N bonds

Abstract
X-Ray studies of the thermodynamically less stable (in solution) diastereoisomeric rotational isomer of 3-(2-bromophenyl)-5-methyl-2-thiohydantion (II) show that the bromine atom is transoid to the 5-methyl group.

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