Energy partitioning in the metastable fragmentation [C3H7]+ → [C3H5]+ + H2
- 1 March 1978
- journal article
- research article
- Published by Wiley in Journal of Mass Spectrometry
- Vol. 13 (3) , 133-134
- https://doi.org/10.1002/oms.1210130304
Abstract
The dish‐topped metastable peak for the fragmentation [C3H7]+ → [allyl]+ + H2 is generated by the threshold fragmentation. The fraction of the reverse activation energy which is partitioned as translational energy of the products is 0.9 ± 0.1. It is proposed that a similar partitioning coefficient applies to the excess internal energy above threshold.Keywords
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