The absorbing boundary method. III. Tunneling decay and scattering resonances
- 1 February 1980
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 72 (3) , 2120-2130
- https://doi.org/10.1063/1.439307
Abstract
The recently developed absorbing boundary method (ABM) is applied to the calculation of tunneling decay rates and corresponding shape resonances in the scattering cross section. The analysis is carried out in terms of the contribution to the density of states from the resonant region of the spatial domain. One‐dimensional test calculations have been carried out using the ABM and several related continuum state methods. While the ABM produces practically useful predictions for the location and shape of the resonance lines, it cannot in its present forms match the accuracy of the best continuum state methods. We have compared results obtained by the ABM (SMA and ISMA), the R‐matrix method, the recently developed CGFEM and Bloch corrected R‐matrix method, the stabilization method of Hazi and Taylor, and a simple pseudo bound state method.Keywords
This publication has 30 references indexed in Scilit:
- Generalisations of the finite-element and R-matrix methodsJournal of Physics B: Atomic and Molecular Physics, 1978
- The interference in the decay of two ½ spins in a molecular medium, studied by the Nakajima–Zwanzig techniqueInternational Journal of Quantum Chemistry, 1977
- Variational correction to Wigner R-matrix theory of scatteringJournal of Physics B: Atomic and Molecular Physics, 1975
- New treatment of the one-particle continuum in nuclear reaction theoryPhysical Review C, 1974
- Newapproach to quantum scattering: TheoryPhysical Review A, 1974
- Quantum mechanical tunnelling in chemistryChemical Society Reviews, 1972
- Solution of Coupled Equations by-Matrix TechniquesPhysical Review B, 1967
- Calculated Spectrum of Quasibound States for H2(1Σg+) and Resonances in H + H ScatteringThe Journal of Chemical Physics, 1967
- Decay Theory of Closely Coupled Unstable StatesPhysical Review B, 1966
- Une formulation unifiée de la théorie des réactions nucléairesNuclear Physics, 1957