Preparation and characterization of tetrakis(tricarbonyldifluororuthenium), tricarbonyltrifluororuthenium, and bis(tricarbonyldifluororuthenium–ruthenium pentafluoride)
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 7,p. 579-583
- https://doi.org/10.1039/dt9760000579
Abstract
The ruthenium carbonyl fluorides, [{Ru(CO)3F2}4], [Ru(CO)3F3], and [{Ru(CO)3F2·RuF5}2] have been prepared in high yield. I.r. spectroscopy, magnetic susceptibility, and e.s.r. spectroscopy have shown that [Ru(CO)3F3] is monomeric but that the structure of [{Ru(CO)3F2·RuF5}2] is closely related to that of [{Ru(CO)3F2}4] and (RuF5)4, which have been previously characterized by single-crystal X-ray diffraction as fluorine-bridged tetramers.Keywords
This publication has 0 references indexed in Scilit: