Formation of a benzosilacyclopentene. Formation of a silacyclopropane by intramolecular insertion of a silylcarbene
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 372a
- https://doi.org/10.1039/c3974000372a
Abstract
Pyrolysis of phenyltrimethylsilyldiazomethane gave 1,1-dimethyl-2,3-benzo-1-silacyclopent-2-ene and the dimerization product of the silylcarbene, whilst photolysis in benzene, gave only the dimerization product.Keywords
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