THE SYSTEM MAGNESIUM OXIDE‐BORIC OXIDE*
- 1 April 1945
- journal article
- Published by Wiley in Journal of the American Ceramic Society
- Vol. 28 (4) , 97-102
- https://doi.org/10.1111/j.1151-2916.1945.tb14519.x
Abstract
Equilibrium In the system has been investigated for compositions from 0.6 to 75 weight per cent MgO. Three intermediate compounds are present. MgO⋅B2O3 melts incongruently at 988°C. to form 2MgO⋅B2O3 and a liquid containing more than 99% B2O3. The other two compounds melt congruently: 2MgO⋅B2O3 at 1340°C. and 3MgO⋅‐B2O3 at 1366°C. At 1142°C., a region of liquid immiscibility extends from 0.6 to 36.0% MgO. Temperatures are accurate within =5°C. Conflicts between these results and those of Toropov and Konovalov (see footnote 8) are discussed.Keywords
This publication has 3 references indexed in Scilit:
- The system: CaO-B2O3Bureau of Standards Journal of Research, 1932
- Some New Standard Melting Points at High TemperaturesPhysical Review B, 1924
- Über die Grenzen der Mischbarkeit von Borsäureanhydrid und Boraten im SchmelzflussZeitschrift für anorganische und allgemeine Chemie, 1904