Pore-space correlations in capillary condensation in Vycor

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Abstract
We use ultrasonic attenuation and light scattering to study spatial correlations in the pores of Vycor on filling and draining with hexane. On filling, the hexane initially adsorbs uniformly, but when capillary condensation occurs, vapor microbubbles are formed and persist until the sample is completely full. However, no long-range correlations of the bubbles are observed. By contrast, on drainage, the empty pores exhibit long-range correlations with a fractal dimension of 2.6. This results from the pore connectivity, suggesting that this behavior can be modeled by invasion percolation.