Palladium-catalysed coupling of trialkylstannyltetrathiafulvalenes with aryl halides

Abstract
Trialkylstannyltetrathiafulvalenes undergo palladium-catalysed cross-and homo-coupling reactions to give aryl-substituted tetrathiafulvalenes and bitetrathiafulvalene; the methodology has been applied to the synthesis of p-phenylenebistetrathiafulvalene and 2,5-thiophenediylbistetrathiafulvalene

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