The photochemistry of two rigid β,γ-cyclopropyl ketones, exo- and endo-tricyclo[3,2,1,02,4]octan-6-one
- 1 January 1975
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 509-510
- https://doi.org/10.1039/c39750000509
Abstract
Photochemical rearrangement of ketones (3) and (9) to bicyclo-octenones (5) and (11), respectively, can be explained by α-cleavage to (12) and (13), followed by stereoelectronically controlled opening to (14) and (15), and then collapse to products.Keywords
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