Complexresonance. Preliminary communication
- 1 January 1949
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 68 (2) , 147-159
- https://doi.org/10.1002/recl.19490680207
Abstract
The colour effects, which occur in the liquid phase in mixtures of quinones or nitro compounds on the one hand and unsaturated or aromatic compounds on the other, are attributed to complexresonance. By this is understood a covalent binding between two molecules, the character of which lies in between that of a single bond and no bond at all.A summary is given of the two types of substances which can exhibit complexresonance with each other and of the phenomena which are associated with complexresonance.Complexresonance is considered as the cause of a number of cases of quenching of fluorescence. In addition it is considered of importance for the formation of the activated complex of certain reactions and for the explanation of some types of enzymatic reactions.Keywords
This publication has 12 references indexed in Scilit:
- The Effects of Pressure, Temperature and Chemical Composition on the Absorption of Light by Mixtures of Aromatic Amines and Nitro CompoundsJournal of the American Chemical Society, 1940
- 287. Complex formation between polynitro-compounds and aromatic hydrocarbons and bases. Part IX. The influence of solvents on the temperature coefficients of colour densitiesJournal of the Chemical Society, 1940
- Structure of Aromatic Polynitro Compound - Hydrocarbon ComplexesNature, 1939
- 253. Complex formation between polynitro-compounds and aromatic hydrocarbons and bases. Part VI. The interaction between s-trinitrobenzene and some aromatic basesJournal of the Chemical Society, 1938
- The Electron Diffraction Investigation of Nitrosyl Chloride and Nitrosyl BromideJournal of the American Chemical Society, 1937
- 128. Complex formation between polynitro-compounds and aromatic hydrocarbons. Part I. Finite reaction ratesJournal of the Chemical Society, 1935
- XL.—The structure of organic molecular compoundsJournal of the Chemical Society, 1929
- Über eine neue sehr empfindliche Farbenreaktion auf Äthylenbindungen, bzw. auf tautomere FormenJournal für Praktische Chemie, 1911
- Ueber Molekularverbindungen von Nitrokörpern mit AminenEuropean Journal of Inorganic Chemistry, 1906
- LVII.—Additive compounds of α- and β-naphthylamine with trinitro-derivatives of benzeneJournal of the Chemical Society, Transactions, 1901