2-Aminothiazole, acetylaminothiazole, dimethylhydantoin and thiohydantoin complexes of tin(IV) and titanium(IV) halides
- 1 January 1974
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 27 (8)
- https://doi.org/10.1071/ch9741827
Abstract
Complexes of the type MX4L2 (M = Sn, Ti; X = Cl, Br, I; L = dimethylhydantoin, thiohydantoin, 2-aminothiazole and 2-acetylaminothiazole) have been prepared and characterized. Infrared spectral studies indicate exocyclic nitrogen of 2:aminothiazole and carbonyl oxygen of all other ligands as the donor site. Far-infrared spectra suggest that dimethylhydantoin and 2-acetylaminothiazole complexes are trans, and 2-aminothiazole and thiohydantoin complexes are cis octahedral.Keywords
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