π-Olefin-Iridium-Komplexe, VII [1] Komplexbildung von Iridium mit Fulvenen / π-Oefin Iridium Complexes, VII [1] Complex Formation of Iridium with Fulvenes
Open Access
- 1 October 1981
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 36 (10) , 1219-1224
- https://doi.org/10.1515/znb-1981-1005
Abstract
Reactions of [Ir(COD)Cl]2 (COD = 1,5-cyclooctadiene) with either i-C3H7MgBr or CH3Li in the presence of dimethyl-and diethylfulvene, respectively, yield complexes of the type [Ir(COD)(C5H4R)] where C5H4R is a cyclopentadienyl ligand. The nature of the substituent R depends on the fulvene as well as on the alkyl reagent. The compounds were characterized by NMR and mass spectra and in one case by X-ray diffraction analysis.Keywords
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