Reaction between iron porphyrins and carbon monoxide. A kinetic model for myoglobin
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 325-326
- https://doi.org/10.1039/c39730000325
Abstract
Kinetic studies of the reaction between carbon monoxide and (piperidine)2Fe(porphyrin) complexes to give (piperidine)Fe(CO)(porphyrin) show that the mechanism involves predissociation to a five-co-ordinate (piperidine)Fe(porphyrin) complex; the data for the protoporphyrin IX system suggest that the model may resemble closely in kinetic properties the active iron site in deoxy-myoglobin and -hemoglobin.Keywords
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