Cumulene complexes of transition metals. Part I. Hexacarbonyldi-iron complexes

1 January 1966

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 594-597
https://doi.org/10.1039/j19660000594

Abstract

Reactions of Ar₂CCBr₂ and XR₂C·CC·CR₂X with iron carbonyls or carbonylates give hexacarbonyldi-iron complexes of butatrienes. The same complexes are also obtained from the reactions of butatrienes with iron carbonyls, thus supporting their formulation. The structures are proposed for compounds of formulæ C₃₄H₂₀Fe₂O₆, C₉H₈FeO₅, and C₁₅H₁₀Fe₂O₇, which are also produced in these reactions.

Keywords

IRON COMPLEXES
HEXACARBONYLDI IRON
STRUCTURES
BUTATRIENES
TRANSITION METALS
GIVE HEXACARBONYLDI
FORMULÆ C34H20FE2O6
CARBONYLATES GIVE

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