Magnetic field induced reversed (Negative) magnetization for electrochemically deposited Tc = 260 K Oxidized Films of Chromium Cyanide Magnets
- 1 July 1997
- journal article
- research article
- Published by Wiley in Advanced Materials
- Vol. 9 (8) , 645-647
- https://doi.org/10.1002/adma.19970090812
Abstract
Molecule‐based magnets with high ordering temperatures Tc (above room temperature) include some mixed‐oxide hexacyanometallates. The example studied here, Cr2.12(CN)6 · ½ H2O (the Figure shows its crystalline and amorphous phases), is shown to have Tc equals; 260 K and exhibit negative (reverse) magnetization. An explanation is suggested for this behavior and the temperature and field dependences of the magnetization. magnified imageKeywords
This publication has 14 references indexed in Scilit:
- Improved Synthesis of the V(tetracyanoethylene)x·y(solvent) Room-Temperature Magnet: Doubling of the Magnetization at Room TemperaturePublished by American Chemical Society (ACS) ,1996
- A room-temperature organometallic magnet based on Prussian blueNature, 1995
- DESIGNER MAGNETSPublished by American Chemical Society (ACS) ,1995
- High-Temperature Molecular Magnets Based on Cyanovanadate Building Blocks: Spontaneous Magnetization at 230 KScience, 1995
- Ferromagnetism of Organic Radical CrystalsJapanese Journal of Applied Physics, 1994
- Molecular Magnetism: A basis for new materialsAdvanced Materials, 1994
- Organic and Organometallic Molecular Magnetic Materials—Designer MagnetsAngewandte Chemie International Edition in English, 1994
- High- T c Molecular-Based Magnets: Ferrimagnetic Mixed-Valence Chromium(III)-Chromium(II) Cyanides with T c at 240 and 190 KelvinScience, 1993
- Spin frustration and metamagnetic behavior in a molecular-based quasi-1D ferrimagnetic chain: (MnTPP)(TCNE)Journal of Applied Physics, 1993
- High-TC molecular-based magnets: a ferromagnetic bimetallic chromium(III)-nickel(II) cyanide with TC = 90 KJournal of the American Chemical Society, 1992