An unexpected cluster rearrangement in the formation of a closo-carbametallaborane from an arachno-carbaborane. The crystal and molecular structure of [1-(PPh3)-2-H-2,2-(PPh3)2-2,10-IrCB8H8]
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1168-1169
- https://doi.org/10.1039/c39830001168
Abstract
A novel closo-iridium(III) complex, [1-(PPh3)-2-H-2,2(PPh3)2-2,10-IrCB8H8], has been isolated as one of several products from the reaction of [IrCl(PPh3)3] with the arachno-[CB8H13]– anion; the position of the cluster carbon atom indicates the process by which the cage rearrangement occurs.Keywords
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