Total synthesis of (±)-cinnamolide and (±)-methylenolactocin–an approach to butenolides using S-alkoxycarbonyl xanthates
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 14,p. 1631-1632
- https://doi.org/10.1039/cc9960001631
Abstract
The total synthesis of (±)-cinnamolide 9 and (±)-methylenolactocin 15 is accomplished using as the key step a radical cyclisation involving alkoxycarbonyl radicals derived from S-alkoxycarbonyl xanthates.Keywords
This publication has 26 references indexed in Scilit:
- A new radical based synthesis of lactams and indolones from dithiocarbonates (xanthates)Tetrahedron Letters, 1994
- Xanthic anhydrides: A novel and convenient source of alkoxythiocarbonyl and alkyl radicals.Tetrahedron, 1993
- Novel radical chain reactions based on O-alkyl tin dithiocarbonatesJournal of the American Chemical Society, 1992
- Synthesis of .gamma.- and .delta.-lactones by free-radical annelation of Se-phenyl selenocarbonatesThe Journal of Organic Chemistry, 1992
- Natural sesquiterpenoidsNatural Product Reports, 1992
- Natural sesquiterpenoidsNatural Product Reports, 1992
- New radical chain reaction of S-alkoxycarbonyl dithiocarbonates: a useful source of alkyl radicals from alcoholsJournal of the American Chemical Society, 1990
- The Design and Application of Free Radical Chain Reactions in Organic Synthesis. Part 2Synthesis, 1988
- Steroids and sex hormones. Part 262. The radical induced stannane reduction of selenoesters and selenocarbonates: A new method for the degradation of carboxylic acids to nor‐alkanes and for desoxygenation of alcohols to alkanesHelvetica Chimica Acta, 1980
- PEROXIDE-INDUCED ADDITIONS OF METHYL FORMATE TO OLEFINSJournal of the American Chemical Society, 1953