Transition metal-catalysed rearrangement of allyl but-3-enoate to hepta-2,6-dienoic or hepta-3,6-dienoic acids
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 793-794
- https://doi.org/10.1039/c39770000793
Abstract
The rearrangement of allyl but-3-enoate to heptadienoic acids is catalysed by nickel and rhodium complexes in the presence of phosphorus-containing ligands and can be driven towards either the 2,6- or the 3,6-isomers through selective hydrogen abstraction.Keywords
This publication has 0 references indexed in Scilit: