Carbon/poly {pyrrole-[(C5Me5)RhIII(bpy)Cl]+} modified electrodes; a molecularly-based material for hydrogen evolution (bpy = 2,2′-bipyridine)
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1259-1261
- https://doi.org/10.1039/c39890001259
Abstract
A rhodium(III) complex containing a 2,2′-bipyridine ligand substituted with pyrrole groups has been anodically electropolymerized on either a Pt or a C electrode; the polymer attached to C acts as an efficient molecularly-based cathode material for hydrogen evolution in aqueous solution (pH 1).Keywords
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