Transition-metal chemistry of dichloromethylene(dimethyl)ammonium chloride; C-chlorocarbene complexes
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 929-930
- https://doi.org/10.1039/c39750000929
Abstract
C-Chlorocarbene d6 complexes of Cr0, MnI, and RhIII, (I)–(V), have been obtained from [Me2NCCl2]+Cl– and the appropriate transition metal complex precursor, by four procedures (a, a′, a″, or b); alternative reaction pathways (c or d) lead to other species, including the electron-rich cluster compound [Co3(CO)9CNMe2].Keywords
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