Pressure induced shifts of CO2 lines: Measurements in the 003–000 band and theoretical analysis

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Abstract
Self-broadened and N2, Ar, He-broadened halfwidth and pressure shift coefficients of the rotational transitions in the 0003–0000 band of 12C16O2 have been measured from laboratory absorption recorded at room temperature with a Fourier transform spectrometer. Comparison is made with the results of a theoretical calculation based on a semiclassical model. Good agreement is obtained for all the IR vibrational bands for which data are available. It has been shown that the shifts mainly originate from vibrational dephasing. Infrared line shifts have been compared with results obtained from stimulated Raman spectroscopy and we show that they are not consistent. A number of possible explanations have been discussed to account for this discrepancy.