The configuration of mitiromycin and its derivation from mitomycin B.
- 1 January 1991
- journal article
- Published by Japan Antibiotics Research Association in The Journal of Antibiotics
- Vol. 44 (3) , 309-312
- https://doi.org/10.7164/antibiotics.44.309
Abstract
The configuration of mitiromycin (2) was first determined by NMR experiments including the NOE technique. The absolute structure of 2 was related to mitomycin B (3) because 2 was derived from 3 under basic conditions. The ketonic form 4 was presumed to be involved in the generation of 2.Keywords
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