A Chemical Equilibrium Estimate of the Aerosols Produced in an Overheated Light Water Reactor Core

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Abstract
The degree of vaporization of light water reactor core materials was estimated using a highly idealized procedure involving (a) specification of the phases that are present for both structural and fuel material, (b) estimation of the vapor pressures exerted by the individual components of each phase, and (c) assuming a degree of vaporization of each phase constituent, allowing equilibration between gaseous and condensed species within the assumed pressure vessel volume. Using this procedure, the aerosol was estimated to consist mainly of silver, indium oxide, cesium hydroxide, and cadmium for pressurized water reactors and cesium hydroxide, cesium iodide, and tellurium for boiling water reactors. If boron is included in the thermodynamic estimate, then boron will significantly alter or dominate the composition of the aerosol in the form of boron oxide and cesium borate. The structural materials make up <9% of the aerosol at 36 to 57 kg, but this figure is in good agreement with estimates from severe accident sequence analysis studies (17 kg) and from Parker (10.7 kg). The SASCHA data are used in NUREG-0772 and give much higher estimates at 295 and 250 kg.