CORRELATION OF 13C–H AND 13C–C–H COUPLING CONSTANTS OF THE FORMYL GROUP IN SUBSTITUTED BENZALDEHYDES WITH HAMMETT σ CONSTANTS
- 5 February 1972
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 1 (2) , 107-110
- https://doi.org/10.1246/cl.1972.107
Abstract
The values of 13C–H and 13C–C–H coupling constants of the formyl group in substituted benzaldehydes followed the Hammett equation. The ρ(JC–H) value was found to be considerably larger than that for substituted toluenes. Values for ρo (JC–H) and ρo(JC–C–H) are also discussed.This publication has 8 references indexed in Scilit:
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