Structure and dynamics of intermediates in asymmetric hydrogenation by rhodium complexes of (2-methoxyphenyl)-P-phenyl-P-(2′-diphenylphosphino)ethylphosphine
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 2469-2471
- https://doi.org/10.1039/c39950002469
Abstract
The four rhodium enamide complexes formed from the title ligand and methyl Z-acetamidocinnamate undergo rapid pair-specific intramolecular exchange and give rise to a single alkylhydride under hydrogen below –40 °C.Keywords
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