Phase separation dynamics: Comparison of experimental results
- 1 December 1983
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 79 (11) , 5588-5594
- https://doi.org/10.1063/1.445679
Abstract
Experimental evidence suggests that phase separation dynamics are insensitive to the molecular details of the system. If time and length are properly scaled, using only experimental data, superposition of phase separation data from metallic alloys, inorganic glasses, small molecule systems, and polymer blends is obtained. An empirical equation, gm=τ−[ln(1+aτ)]/ln(τ), where a=0.05, fits the observed data. It is also shown that power law relations which have been widely applied to describe the time behavior of the structure factor are experimentally valid over only narrow time windows are not applicable throughout the entire phase separation process.Keywords
This publication has 19 references indexed in Scilit:
- Computer-Simulation Dynamics of an Unstable Two-Dimensional Fluid: Time-Dependent Morphology and ScalingPhysical Review Letters, 1982
- Late stages of spinodal decomposition in binary mixturesPhysical Review A, 1979
- On the theory of spinodal decomposition in solid and liquid binary mixturesZeitschrift für Physik B Condensed Matter, 1978
- Theory of Early Stage Spinodal Decomposition in Fluids near the Critical Point. IIProgress of Theoretical Physics, 1978
- Theory of spinodal decomposition in critical fluid mixturesPhysics Letters A, 1978
- Time evolution of a quenched binary alloy. II. Computer simulation of a three-dimensional model systemPhysical Review B, 1975
- New computational method in the theory of spinodal decompositionPhysical Review A, 1975
- Brownian motion in spinodal decompositionActa Metallurgica, 1970
- Phase Separation by Spinodal Decomposition in Isotropic SystemsThe Journal of Chemical Physics, 1965
- The kinetics of precipitation from supersaturated solid solutionsJournal of Physics and Chemistry of Solids, 1961