X-Ray molecular structure and reactions of bis(styrene)bis(triphenylphosphine)ruthenium(0); the first sixteen-electron ruthenium(0) species
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 463-464
- https://doi.org/10.1039/c39780000463
Abstract
The complex originally formulated as Ru-(styrene)(PPh3)3 has been shown by X-ray study to be Ru(styrene)2(PPh3)2, (containing solvent); the formation of dihydridotetrakis(triphenylphosphine)ruthenium(II), RuH2(PPh3)4, on interaction of the complex with hydrocarbons has been studied and the source of hydride attributed to triphenylphosphine.Keywords
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