Spectrum of SO. Evidence for a new 3? state
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 78 (8) , 1139-1147
- https://doi.org/10.1039/f29827801139
Abstract
A rotational analysis has been carried out on the 3Π1 and 3Π0 sub-bands of the 1–0 band of the A3Π–X3Σ spectrum of SO obtained previously. A perturbation present on the v′= 1, J′= 15 level of the F2(3Π1) component of the A3Π state is shown to be consistent with that arising from interaction with a 3Δ state. Using calculations of Dixon et al., coupled with an empirical correction to the calculated term value of the 3Δ state, a crude potential is constructed which would cross the A state at v′= 1.Keywords
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